Molybdic acid

Molybdic acid
Names
	Other names Molybdic(VI) acid
Identifiers
CAS Number	7782-91-4 ; monohydrate: 13462-95-8; dihydrate: 25942-34-1;
3D model (JSmol)	Interactive image;
ChEBI	CHEBI:25371;
ChemSpider	74188;
ECHA InfoCard	100.029.063
EC Number	231-970-5;
KEGG	C06232;
PubChem CID	82208;
UNII	I96N991J1N ;
CompTox Dashboard (EPA)	DTXSID20894105 ;
	InChI InChI=1S/Mo.2H2O.2O/h;21H2;;/q+2;;;;/p-2 Key: VLAPMBHFAWRUQP-UHFFFAOYSA-L; InChI=1/Mo.2H2O.2O/h;21H2;;/q+2;;;;/p-2/rH2MoO4/c2-1(3,4)5/h2-3H Key: VLAPMBHFAWRUQP-LHLUJLTBAG;
	SMILES O=[Mo](=O)(O)O;
Properties
Chemical formula	MoO3·H2O
Molar mass	161.95 g mol−1
Appearance	white crystals (anhydrous) ; yellow crystals (monohydrate)
Density	3.112 g/cm3 (anhydrous) ; 3.124 g/cm3 (monohydrate)
Melting point	300 °C (572 °F; 573 K)
Solubility in water	1510 mg dm−3 Soluble in 10% ammonia 35gm/lt
Structure
Crystal structure	hexagonal (anhydrous) ; monoclinic (monohydrate)
Hazards
	GHS labelling:
Pictograms
Signal word	Warning
Hazard statements	H319, H335, H373
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Molybdic acid refers to hydrated forms of molybdenum trioxide and related species. The monohydrate (MoO₃·H₂O) and the dihydrate (MoO₃·2H₂O) are well characterized. They are yellow diamagnetic solids.

Structure of the solids

Portion of one layer of hydrated molybdic acid, MoO₃·(H₂O)₂.

Solid forms of molybdic acid are coordination polymers. The monohydrate MoO₃·H₂O consists of layers of octahedrally coordinated MoO₅·(H₂O) units where 4 vertices are shared.^[3] The dihydrate (image shown above) has the same layer structure with the "extra" H₂O molecule intercalated between the layers.^[4]

Structure of molybdic acid in solution

In acidified aqueous solutions of molybdic acid, the complex MoO₃(H₂O)₃ is observed. Once again, molybdenum adopts octahedral molecular geometry, probably with three oxo ligands and three aquo ligands.^[5]

The salts of molybdic acid are called molybdates. They arise by adding base to solutions of molybdic acid.

Applications

Many molybdenum oxides are used as heterogeneous catalysts, e.g. for oxidations. Molybdic acid and its salts are used to make the Froehde reagent for the presumptive identification of alkaloids.

References

^ ^a ^b "Molybdic acid | 7782-91-4". Chemicalbook.com. Retrieved 2012-08-23.
^ "C&L Inventory". echa.europa.eu.
^ Wells A.F. (1984) Structural Inorganic Chemistry 5th edition Oxford Science Publications ISBN 0-19-855370-6
^ Krebs, B. (1972). "Die Kristallstruktur von MoO₃(H₂O)₂". Acta Crystallographica B. 28 (7): 2222–2231. Bibcode:1972AcCrB..28.2222K. doi:10.1107/S0567740872005849.
^ Solution structure of molybdic acid from Raman spectroscopy and DFT analysis, Oyerindea O.F., Week C.L., Anbarb A.D., Spiro T.G. Inorganica Chimica Acta, 361, 4, (2008), 1000-1007, doi:10.1016/j.ica.2007.06.025

[a1-1] "Molybdic acid | 7782-91-4". Chemicalbook.com. Retrieved 2012-08-23.

[2] "C&L Inventory". echa.europa.eu.

[Wells-3] Wells A.F. (1984) Structural Inorganic Chemistry 5th edition Oxford Science Publications ISBN 0-19-855370-6

[4] Krebs, B. (1972). "Die Kristallstruktur von MoO₃(H₂O)₂". Acta Crystallographica B. 28 (7): 2222–2231. Bibcode:1972AcCrB..28.2222K. doi:10.1107/S0567740872005849.

[5] Solution structure of molybdic acid from Raman spectroscopy and DFT analysis, Oyerindea O.F., Week C.L., Anbarb A.D., Spiro T.G. Inorganica Chimica Acta, 361, 4, (2008), 1000-1007, doi:10.1016/j.ica.2007.06.025

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