Hasubanan

Hasubanan
Names
	IUPAC name (3aS-cis)-2,3,4,5-Tetrahydro-3a,9b-butano-1H-benz[e]indole
Identifiers
CAS Number	14510-67-9 ;
3D model (JSmol)	Interactive image;
ChEBI	CHEBI:35647 ;
ChemSpider	20152973 ;
PubChem CID	6857499;
UNII	8K38RGP7SY ;
CompTox Dashboard (EPA)	DTXSID60425891 ;
	InChI InChI=1S/C16H21N/c1-2-6-14-13(5-1)7-10-16-9-4-3-8-15(14,16)11-12-17-16/h1-2,5-6,17H,3-4,7-12H2/t15-,16+/m1/s1 Key: RKWPQIQYRNOTMT-CVEARBPZSA-N ; InChI=1/C16H21N/c1-2-6-14-13(5-1)7-10-16-9-4-3-8-15(14,16)11-12-17-16/h1-2,5-6,17H,3-4,7-12H2/t15-,16+/m1/s1 Key: RKWPQIQYRNOTMT-CVEARBPZBP;
	SMILES C2C[C@]14CCCC[C@@]4(CCN1)c3ccccc23;
Properties
Chemical formula	C16H21N
Molar mass	227.351 g·mol−1
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

Hasubanan is an alkaloid with the chemical formula of C₁₆H₂₁N. It forms the central core of a class of alkaloids known collectively as hasubanans.^[1] The compound is derived from reticuline, as is morphinan, but is comparatively more oxidized and rearranged. It is similar to acutumine.

Various alkaloids of this family have been synthesized in the laboratories.^[2]

References

^ Zhang H, Yue J (2005). "Hasubanan type alkaloids from Stephania longa". J Nat Prod. 68 (8): 1201–7. doi:10.1021/np0500833. PMID 16124761.
^ Ikonnikova, Viktoria A.; Baranov, Mikhail S.; Mikhaylov, Andrey A. (2022-07-18). "Developments in the Synthesis of Hasubanan Alkaloids". European Journal of Organic Chemistry. 2022 (31): ejoc.202200675. doi:10.1002/ejoc.202200675. ISSN 1434-193X. S2CID 250661115.

External links

Synthesis at chem.wisc.edu

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[1] Zhang H, Yue J (2005). "Hasubanan type alkaloids from Stephania longa". J Nat Prod. 68 (8): 1201–7. doi:10.1021/np0500833. PMID 16124761.

[2] Ikonnikova, Viktoria A.; Baranov, Mikhail S.; Mikhaylov, Andrey A. (2022-07-18). "Developments in the Synthesis of Hasubanan Alkaloids". European Journal of Organic Chemistry. 2022 (31): ejoc.202200675. doi:10.1002/ejoc.202200675. ISSN 1434-193X. S2CID 250661115.

[1]

[2]

See also

References

External links